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Stratospheric Ozone (Global)
Contact: Lucien Froidevaux



Summary

The stratospheric ozone (O3) layer (near 20 km altitude) is an absorber of ultraviolet light from the sun; this absorption protects humans from the potentially deadly effects of skin cancer, and can also shield animals and the marine food chain, as well as plants, from undesirable UV-related consequences. Health effects tied to excessive UV exposure include skin cancer, cataracts, and a decline of the immune response system; while there are significant changes in average UV exposure from low to high latitudes, additional exposure (at any latitude) represents some increase in the risks. Decreases in the ozone layer have therefore been a cornerstone of atmospheric research for the past several decades, motivated by the realisation that industrial release of chlorofluorocarbon (CFC) gases at the Earth's surface were linked to a gradual depletion of the ozone layer, as well as the seasonal "ozone hole" phenomenon over Antarctica caused by enhancements in the ozone-destroying forms of chlorine and bromine in the northern hemisphere during the cold winter and spring periods. The different variations in ozone between the northern and southern hemispheres are related to the interplay of dynamical and chemical effects. A circling whirlpool of winds isolates the so-called polar vortex region at high latitudes in winter. More vigorous wave activity in the North leads to a shorter-lived winter polar vortex than in the South, and this reduces the net ozone loss in the northern hemisphere. On a global scale, ozone depletion is typically measured with respect to pre-1980 abundances; values of overhead (column) ozone abundances in the past few years have been lower than the pre-1980 levels by 3 to 6% (for mid- to high latitudes in the North and South, respectively). Thanks to internationally-agreed reductions in CFC emissions after the 1987 Montreal Protocol on Subtances that Deplete the Ozone Layer (with its many subsequent amendments), global ozone is expected to recover to pre-1980 levels in the 2nd half of the 21st century. The slow recovery process arises because of the very long lifetime of the main CFC gases in the upper atmosphere (sunlight destroys these compounds very slowly). There is mounting evidence that a slow path towards such a recovery is being achieved, although continued attention to unexpected chemistry and the variations in ozone is still a very useful endeavor.

NASA's ozonewatch website provides up-to-date information on the status of the ozone layer and the ozone hole over the South Pole. A summary of the history of ozone research and the relationship between UV radiation and ozone can be found here: http://www.skincancer.org/ozone-and-uv-where-are-we-now.html. Research and results regarding environmental effects of ozone depletion can be found, for example, in the following location: http://www.gcrio.org/ozone/toc.html. Based on accumulated research of the Earth's atmospheric composition, scientific consensus reports are published every four years about the state of the ozone layer and the chemical and dynamical effects surrounding the variations in stratospheric ozone. See the following link for access to the 2006 Scientific Assessment of ozone depletion, with "Twenty questions and answers" and an Executive Summary, in addition to the more extensive and detailed research and results: http://www.wmo.int/pages/prog/arep/gaw/ozone_2006/ozone_asst_report.html.

Besides health-related concerns, the study of ozone and the distribution of other gases in the Earth's atmosphere is an important process to help understand atmospheric behavior and to help predict future global change. The Aura satellite is continuing its measurements of ozone and many other gases on a global scale, using both the MLS and OMI instruments (since August, 2004). MLS provides a vertically-resolved view of changes in ozone, with profiles being measured on a roughly 3 km vertical grid, every 170 km around the orbit (for about 3500 profiles every 24 hours). Ozone and related datasets are also being connected to previous global satellite measurements, so that data records can be constructed and preserved for studies of long-term changes in atmospheric composition. More detailed MLS-derived information and scientific publications relating to ozone can be found on the MLS website (http://mls.jpl.nasa.gov under "Publications"); this includes the use of MLS data for investigations of polar ozone loss, and the inference of changes in tropospheric ozone through the combined usage of OMI (total column ozone) and MLS (stratospheric column) measurements.


MLS-related publications concerning global stratospheric ozone

2011

  1. Dragani, R., "On the quality of the ERA-Interim ozone reanalyses: comparisons with satellite data", num 137, 2011. Preprint
  2. Fiorucci, I., "Revising the retrieval technique of a long-term stratospheric HNO3 data set: from a constrained matrix inversion to the optimal estimation algorithm", vol doi:10.5194/angeo-29-1317-2011, num 29, 2011. Preprint
  3. Jackson, D.R., "Low-ozone events in the southern polar summer as indicated by Met Office ozone analyses", vol doi:10.1029/2010JD014858, num 116, 2011. Reprint Preprint
  4. Kroon, M., "Validation of operational ozone profiles from the Ozone Monitoring Instrument", vol doi:10.1029/2010JD015100, num 116, 2011. Reprint Preprint
  5. Nair, P.J., "Coherence of long-term stratospheric ozone vertical distribution time series used for the study of ozone recovery at a northern mid-latitude station", vol doi:10.5194/acp-11-4957-2011, num 11, 2011. Reprint Preprint
  6. Santee, M.L., "Trace gas evolution in the lowermost stratosphere from Aura Microwave Limb Sounder measurements", vol 10.1029/2011JD015590, num 116, 2011. Preprint
  7. Zhang, L., "Impacts of 2006 Indonesian fires and dynamics on tropical upper tropospheric carbon monoxide and ozone", vol doi:10.5194/acp-11-10929-2011, pgs. 11, 2011. Preprint
  8. Ziemke, J.R., "A global climatology of tropospheric and stratospheric ozone derived from Aura OMI and MLS measurements", vol 10.5194/acp-11-9237-2011, num 11, 2011. Preprint

2010

  1. Haigh, J.D., "An influence of solar spectral variations on radiative forcing of climate", vol doi:10.1038/nature09426, num 467, 2010. Reprint Preprint
  2. Hegglin, M.I., "Multimodel assessment of the upper troposphere and lower stratosphere: Extratropics", vol doi:10.1029/2010JD013884, num 115, 2010. Reprint Preprint
  3. Huang, F.T., "Ozone diurnal variations in the stratosphere and lower mesosphere, based on measurements from SABER and TIMED", vol doi:10.1029/2010JD014484, num 115, 2010. Reprint Preprint
  4. Kikuchi, K., "Overview and early results of the Superconducting Submillimeter Wave Limb-Emission Sounder (SMILES)", vol doi:10.1029/2010JD014379, num 115, 2010. Reprint Preprint

2009

  1. Joiner, J., "Accurate satellite-derived estimates of the tropospheric ozone impact on the global radiation budget", num 9, 2009. Reprint Preprint

2008

  1. Harvey, V.L., "Low-ozone pockets observed by EOS-MLS", vol doi:10.1029/2007JD009181, num 113, 2008. Reprint Preprint
  2. Hegglin, M.I., "Validation of ACE-FTS satellite date in the upper troposphere/lower stratosphere (UTLS) using non-coincident measurements", num 8, 2008. Reprint Preprint
  3. McConnell, J.C., "Stratospheric Ozone Chemistry", vol doi:10.3137/ao.460104, num 46, pgs. No. 1, 2008. Reprint Preprint
  4. Migliorini, S., "Evaluation of ozone total column measurements by the Ozone Monitoring Instrument using a data assimilation system", vol doi:10.1029/2007JD008779, num 113, 2008. Preprint

2007

  1. Chandra, S., "Effects of the 2004 El Nino on tropospheric ozone and water vapor", vol doi:10.1029/2006GL028779, num 34, 2007. Preprint
  2. Kovalenko, L.J., "Observed and Modeled HOCl Profiles in the Midlatitude Stratosphere: Implication for Ozone Loss", vol doi:10.1029/2007GL031100, num 34, 2007. Reprint Preprint
  3. Manney, G.L., "Solar Occultation Satellite Data and Derived Meteorological Products: Sampling Issues and Comparisons with Aura MLS", vol doi:10.1029/2007JD008709, num 112, 2007. Reprint Preprint
  4. Randel, W.J., "A large annual cycle in ozone above the tropical tropopause linked to the Brewer-Dobson circulation", vol doi:10.1175/2007JAS2409.1, num 64, 2007. Reprint Preprint
  5. Yang, Q., "Midlatitude tropospheric ozone columns derived from the Aura Ozone Monitoring Instrument and Microwave Limb Sounder measurements", vol doi:10.1029/2007JD008528, num 112, 2007. Preprint
  6. Ziemke, J.R., "Intra-seasonal variability in tropospheric ozone and water vapor in the tropics", vol doi:10.1029/2007GL030965, num 34, 2007. Preprint

2006

  1. Folkins, I., "Testing convective parameterizations with tropical measurements of HNO3, CO, H2O, and O3: Implications fotr the water vapor budget", vol doi:10.1029/2006JD007325, num 111, 2006. Reprint Preprint

2005

  1. Randall, C.E., "Reconstruction and simulation of stratospheric ozone distributions in the 2002 Austral winter", num 62, 2005. Preprint

2002

  1. Struthers, H., "Assimilation of Ozone Profiles and Total Column Measurements into a Global General Circulation Model", vol doi:10.1029/2001JD000957, num 107, pgs. D20, 2002. Reprint Preprint

2001

  1. Azeem, S M.I., "Observations of the 2-day wave in UARS MLS temperature and ozone measurements", num 28, pgs. D16, 2001. Preprint

1999

  1. Solomon, S., "Stratospheric ozone depletion: A review of concepts and history", num 37, 1999. Preprint

1998

  1. Levelt, P.F., "Assimilation of the MLS ozone measurements in the global three-dimensional chemistry transport model ROSE", num 25, 1998. Preprint
  2. Morris, G.A., "Low ozone pockets explained", num 103, pgs. D3, 1998. Preprint
  3. Nair, H., "Localized Rapid Ozone Loss in the Northern Winter Stratosphere: An Analysis of UARS Observations", num 103, pgs. D1, 1998. Preprint

1997

  1. Pumphrey, H.C., "Water Vapour and Ozone in the Mesosphere as measured by UARS MLS", num 24, 1997. Preprint

1995

  1. Canziani, P.O., "Equatorial Kelvin wave variability during 1992 and 1993", num 100, pgs. D3, 1995. Preprint
  2. Manney, G.L., "Formation of low ozone pockets in the middle stratosphere anticyclone during winter", num 100, pgs. D7, 1995. Reprint Preprint
  3. Manney, G.L., "Lagrangian transport calculations using UARS data. Part II: Ozone", num 52, 1995. Preprint
  4. Randel, W.J., "Ozone and temperature changes in the stratosphere following the eruption of Mount Pinatubo", num 100, pgs. D8, 1995. Preprint


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